In a large mixing bowl, whisk together the flour, sugar, baking powder, baking soda, and salt.
Add the cold butter pieces and toss in the flour mixture.
Using a pastry cutter or fork, cut the butter into the flour until the mixture resembles coarse meal and there are larger pea-sized chunks of butter throughout.
It is important for the butter to remain extremely cold throughout the process. If warms too much, transfer the entire bowl to a freezer for 5 to 10 minutes to chill.
In a measuring cup, whisk together the buttermilk and egg. Create a well in the center of the dry ingredients and add the buttermilk mixture.
Using a wooden spoon, stir the wet ingredients into the flour mixture until it just comes together and the flour has just absorbed. It will be shaggy.
Transfer the dough and any dry remaining bits to a lightly floured countertop.
Knead the dough until it comes together, dusting the dough lightly with flour as necessary to prevent it from sticking to your hands or the countertop. Press the dough into a disc that is roughly 3/4-inch thick.
Fold the dough over itself 2 to 3 times, this will help create layers. Use a 2.5-inch biscuit cutter (dipped in flour to prevent sticking) to cut out 6 shortcakes.
Do not twist the cutter as you cut the dough, as this will prevent them from rising evenly.
Press the remaining scraps together to cut out another 1 to 2 biscuits.
Transfer the scones evenly on the lined sheet pan, setting apart by several inches.
Lightly brush the tops of the scones with egg wash and sprinkle with demerara sugar.
Bake at 450 degrees for 10 to 15 minutes, or until tall and golden brown.
Transfer to a wire rack to cool as you prepare the lemon curd whipped cream.